My favorite pass in SBLI is the 3rd&10 on the 9 to Hogan to start the final Q4 drive:
There are a couple of interesting facets of this pass.
Hogan cuts his out route but never looks back at Brady until after the pass is thrown. Brady throws the ball before Hogan even finished his cut, and starts the throw while Hogan is still running straight downfield. He is also throwing to a cornerback: if for some reason Hogan's timing or route running is inaccurate, it will be an interception.
I very rarely see receivers run a route like this without making any eye contact with the quarterback. Actually I'm not sure I can think of any examples. Normally where there is no eye contact, the route is either short of the receiver (which Hogan also did in another play) or beyond him, when the QB knows that if he overthrows the receiver already beat the cornerback so there won't be an interception. To throw
before the cut like that on such a long pass is impressive.
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The video link above has the broadcast feed, I'm enclosing a few stills from the all-22.